(E)-3-[4-(Hex­yloxy)phen­yl]-1-(4-hydroxy­phen­yl)prop-2-en-1-one

نویسندگان

  • Ibrahim Abdul Razak
  • Hoong-Kun Fun
  • Zainab Ngaini
  • Norashikin Irdawaty Abd Rahman
  • Hasnain Hussain
چکیده

In the title compound, C(21)H(24)O(3), the enone group adopts an s-cis conformation. The planes of the aromatic rings are inclined at an angle of 6.1 (1)°. The alk-oxy tail is not linear, with the maximum deviation from the least-squares plane being 0.375 (2) Å. Mol-ecules are connected into extended chains along the a axis through O-H⋯O(carbon-yl) hydrogen bonds and are inter-linked via C-H⋯O inter-actions to form a two-dimensional array parallel to the ab plane.

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منابع مشابه

(E)-1-[4-(Hex­yloxy)phen­yl]-3-(4-hy­droxy­phen­yl)prop-2-en-1-one

In the title compound, C(21)H(24)O(3), inter-molecular O-H⋯O and C-H⋯O inter-actions form bifurcated acceptor bonds, generating R(2) (1)(6) ring motifs. These ring motifs link the mol-ecules into extended chains along [010]. The crystal structure is further stabilized by C-H⋯π inter-actions.

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Crystal structures of three 1-[4-(4-bromo­but­oxy)­phen­yl] chalcone derivatives: (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-phenyl­prop-2-en-1-one, (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(4-meth­oxy­phen­yl)prop-2-en-1-one and (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one

The crystal structures of three chalcones with a bromo-substituted but-oxy side chain, viz. (E)-1-[4-(4-bromo-but-oxy)-phen-yl]-3-phenyl-prop-2-en-1-one, C19H19BrO2, (I), (E)-1-[4-(4-bromo-but-oxy)-phen-yl]-3-(4-meth-oxy-phen-yl)prop-2-en-1-one, C20H21BrO3, (II), and (E)-1-[4-(4-bromo-but-oxy)-phen-yl]-3-(3,4-di-meth-oxy-phen-yl)prop-2-en-1-one, C21H23BrO4, (III), are reported. In all mol-ecule...

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(E)-3-[4-(Hex­yloxy)phen­yl]-1-(2-hydroxy­phen­yl)prop-2-en-1-one

In the title compound, C(21)H(24)O(3), the conformation of the enone group is s-cis. The benzene rings are inclined at an angle of 7.9 (1)°. The alk-oxy tail is planar, with a maximum deviation from the least-squares plane of 0.009 (2) Å, and adopts a trans conformation throughout. An intra-molecular O-H⋯O inter-action between the keto and hydr-oxy groups forms S(6) ring motifs. In the crystal,...

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(E)-1-[4-(Hex­yloxy)phen­yl]-3-(2-hy­droxy­phen­yl)prop-2-en-1-one

In the title compound, C(21)H(24)O(3), the enone moiety adopts an s-cis conformation and the dihedral angle between the benzene rings is 12.89 (6)°. The hex-yloxy tail adopts an extended conformation. In the crystal, inversion dimers are linked by pairs of O-H⋯O hydrogen bonds and pairs of C-H⋯O inter-actions, forming two R(2) (2)(7) and one R(2) (2)(10) loops. The dimers are then arranged into...

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(E)-3-[4-(Dec­yloxy)phen­yl]-1-(4-hydroxy­phen­yl)prop-2-en-1-one

In the title compound, C(25)H(32)O(3), the enone group adopts an s-cis conformation. The alk-oxy unit is nearly planar and is in a trans conformation. The two benzene rings make a dihedral angle of 18.87 (9)°. In the crystal structure, mol-ecules are linked into chains running along the a axis by inter-molecular O-H⋯O hydrogen bonds involving the hydr-oxy and keto groups. The chains are crossli...

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009